Volume 34 Issue 4
Dec.  2020
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WANG Qinsheng, YANG Yongqiang, WANG Ling, ZHANG Yan. Surface Morphology Control and Surface Enhanced Raman Scattering Effect of GO/Au/Ag Composite[J]. Journal of Shanghai University of Engineering Science, 2020, 34(4): 314-319.
Citation: WANG Qinsheng, YANG Yongqiang, WANG Ling, ZHANG Yan. Surface Morphology Control and Surface Enhanced Raman Scattering Effect of GO/Au/Ag Composite[J]. Journal of Shanghai University of Engineering Science, 2020, 34(4): 314-319.

Surface Morphology Control and Surface Enhanced Raman Scattering Effect of GO/Au/Ag Composite

  • Received Date: 2019-11-13
  • Publish Date: 2020-12-30
  • Surface enhanced Raman scattering (SERS) has attracted much attentions in the field of chemical detection because of its high sensitivity and nondestructive detection. Graphene oxide/Au/Ag (GO/Au/Ag) composites were prepared by in-situ chemical reduction method. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and Ultraviolet-visible spctrophotometer (UV) were used to characterize the structure of the composites, and the effect of Au/Ag ratio on the morphology and SERS of composites were strudied. Rhodamine 6G (R6G) was used as the probe molecule to study the influence of composites morpfology on surface enhanced SERS. The result show that GO/Au/Ag composites have good SERS enhanced effect, and the SERS signal intensity is related to the surface morphology and the content (mass fraction) of Au and Ag. The increase of surface roughness of Au/Ag particles and the content of Au and Ag could significantly increased the SERS effect of GO/Au/Ag composites.
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  • [1]
    FLEISCHMANN M, HENDRA P J, MCQUILLAN A J. Raman spectra of pyridine adsorbed at a silver electrode[J] . Chemical Physics Letters,1974,26(2):163 − 166.
    [2]
    LE RU E, BLACKIE E J, MEYER M, et al. Surface enhanced Raman scattering enhancement factors: a comprehensive study[J] . Journal of Physical Chemistry C,2007,111(37):13794 − 13803.
    [3]
    WANG K Q, SUN D W, PU H B, et al. Surface-enhanced Raman scattering of core-shell Au@Ag nanoparticles aggregates for rapid detection of difenoconazole in grapes[J] . Talanta,2019,191:449 − 456.
    [4]
    D’ANDREA C, FAZIO B, GUCCIARDI P G, et al. SERS enhancement and field confinement in nanosensors based on self-organized gold nanowires produced by ion-beam sputtering[J] . Journal of Physical Chemistry C,2014,118(118):8571 − 8580.
    [5]
    GUO P Z, SIKDAR D, HUANG X P, et al. Plasmonic core-shell nanoparticles for SERS detection of the pesticide thiram: size- and shape-dependent Raman enhancement[J] . Nanoscale,2015,7(7):2862 − 2868.
    [6]
    MILLO D, BONIFACIO A, MONCELLI M R, et al. Characterization of hybrid bilayer membranes on silver electrodes as biocompatible SERS substrates to study membrane–protein interactions[J] . Colloids and Surfaces B: Biointerfaces,2010,81(1):212 − 216.
    [7]
    BAI T T, SUN J F, CHE R C, et al. Controllable preparation of core–shell Au–Ag nanoshuttles with improved refractive index sensitivity and SERS activity[J] . ACS Applied Materials & Interfaces,2014,6(6):3331 − 3340.
    [8]
    MA P Y, LIANG F H, DIAO Q P, et al. Selective and sensitive SERS sensor for detection of Hg2+ in environmental water base on rhodamine-bonded and amino group functionalized SiO2-coated Au-Ag core-shell nanorods[J] . RSC Advances,2015,5(41):32168 − 32174.
    [9]
    HAN X X, CHEN L,KUHLMANN U, et al. Magnetic titanium dioxide nanocomposites for surface-enhanced resonance Raman spectroscopic determination and degradation of toxic anilines and phenols[J] . Angewandte Chemie International Edition,2014,53(53):2481 − 2484.
    [10]
    ZHANG J L,YANG H J,SHEN G X, et al. Reduction of graphene oxide via L-ascorbic acid[J] . Chemical Communications,2010,47(7):1112 − 150.
    [11]
    ALEKSANDRA W, KAMAT P V. Reduced graphene oxide and porphyrin. An interactive affair in 2-D[J] . ACS Nano,2010,4(11):6697 − 6706.
    [12]
    EMERY J D, WANG Q H, ZARROUATI M, et al. Structural analysis of PTCDA monolayers on epitaxial graphene with ultra-high vacuum scanning tunneling microscopy and high-resolution X-ray reflectivity[J] . Surface Science,2011,605(17-18):1685 − 1693.
    [13]
    XIE L M, LING X, FANG Y, et al. Graphene as a substrate to suppress fluorescence in resonance Raman spectroscopy[J] . Journal of the American Chemical Society,2009,131(29):9890 − 9891.
    [14]
    OTTO A. The ‘chemical’ (electronic) contribution to surface‐enhanced Raman scattering[J] . Journal of Raman Spectroscopy,2005,36(36):497 − 509.
    [15]
    ZHANG M J, LENG Y D, HUANG J, et al. Surface-enhanced Raman scattering of dipolar molecules by the graphene Fermi surface modulation with different dipole moments[J] . Applied Surface Science,2017,(425):654 − 662.
    [16]
    JUNG N, CROWTHER A C, KIM N, et al. Raman enhancement on graphene: adsorbed and intercalated molecular species[J] . ACS Nano,2010,4(11):7005 − 7013.
    [17]
    WANG L, ZHANG Y, YANG Y Q,et al. Strong dependence of surface enhanced Raman scattering on structure of graphene oxide film[J] . Materials,2018,11(7):1199.
    [18]
    ZHENG X L, PENG Y S, YANG Y, et al. Hydrothermal reduction of graphene oxide; effect on surface-enhanced Raman scattering[J] . Journal of Raman Spectroscopy,2017,48(48):97 − 103.
    [19]
    YANG H P, HU H L, NI Z H, et al. Comparison of surface-enhanced Raman scattering on graphene oxide, reduced graphene oxide and graphene surfaces[J] . Carbon,2013,(62):422 − 429.
    [20]
    YANG Y Q, WANG L, WANG Q S, et al. Synthesis of GO/Au/Ag nanocomposite with excellent surface enhanced Raman scattering effect[J] . Journal of Physics. Conference Series,2020,1622(1):012067.
    [21]
    HUMMERS W S, OFFEMAN R E. Preparation of graphitic oxide[J] . Journal of the American Chemical Society,1958,80(6):1339.
    [22]
    ROBINSON J T, TABAKMAN S M, LIANG Y Y, et al. Ultrasmall reduced graphene oxide with high near-infrared absorbance for photothermal therapy[J] . Journal of the American Chemical Society,2011,133(133):6825 − 6831.
    [23]
    王玲, 张艳, 张婧, 等. Au@石墨烯量子点复合材料的制备及表面增强拉曼散射应用[J] . 新型炭材料,2019,34(6):606 − 610.
    [24]
    HIROYUKI W, NORIHIKO H, YASUSHI I, et al. DFT vibrational calculations of rhodamine 6G adsorbed on silver: analysis of tip-enhanced Raman spectroscopy[J] . Journal of Physical Chemistry B,2005(109):5012 − 5020.
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